Heterogeneous Enantioselective Hydrogenation

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Beschreibung

Heterogeneous Enantioselective Hydrogenation: Theory and Practice reviews the development of enantioselective hydrogenation reaction catalysts. It looks at the first relatively ineffective catalysts right through to modern highly effective enantioselective catalytic systems, comparable in their efficiency to chiral metal complexes and enzymatic systems. The book begins with a summary of the first work on heterogeneous metal catalysts, which showed only the principal possibilities of enantioselective reactions. It then elaborates on metal catalysts which have enantioselectivities close to 100%. Finally, the practical utilization of chiral catalytic systems in processes of hydrogenation is described. The alpha- and beta-hydroxy carboxylic acid esters produced are precursors for manufacturing many synthones used for medicines as well as for monomers used for biodegradable polyesters, both of which have important practical applications.

The volume summarizes more than 800 scientific papers in the field of enantioselective catalytic hydrogenation reactions, mainly those using heterogeneous metal catalysts. It provides detailed explanations of special techniques for the preparation of effective dissymmetric catalysts which provide highly efficient catalytic systems.



Includes recommendations for the practical utilization of recently described preparations of metal catalysts

Complete coverage of enantioselective hydrogenation reaction catalysts

Describes metal catalysts which have enantioselectivities close to 100%



Klappentext

Heterogeneous Enantioselective Hydrogenation: Theory and Practice reviews the development of enantioselective hydrogenation reaction catalysts. The book looks at the first relatively ineffective catalysts right through to modern highly effective enantioselective catalytic systems, comparable in their efficiency to chiral metal complexes and enzymatic systems. The book begins with a summary of the first work on heterogeneous metal catalysts, which showed only the principal possibilities of enantioselective reactions. The book then elaborates on metal catalysts which have enantioselectivities close to 100%. Finally, the book describes the practical utilization of chiral catalytic systems in processes of hydrogenation. The a - and b -hydroxy carboxylic acid esters produced are precursors for manufacturing many synthones used for medicines as well as for monomers used for biodegradable polyesters, both of which have important practical applications. The book summarizes more than 800 scientific papers in the field of enantioselective catalytic hydrogenation reactions, mainly those using heterogeneous metal catalysts. It provides detailed explanations of special techniques for the preparation of effective dissymmetric catalysts which provide highly efficient catalytic systems.

This book differs from previous publications by virtue of the recommendations for the practical utilization of recently described preparations of metal catalysts.

Heterogeneous Enantioselective Hydrogenation: Theory and Practice will be an invaluable resource to catalysis researchers as well as to those utilizing the technology.



Zusammenfassung

Heterogeneous Enantioselective Hydrogenation: Theory and Practice reviews the development of enantioselective hydrogenation reaction catalysts. It looks at the first relatively ineffective catalysts right through to modern highly effective enantioselective catalytic systems, comparable in their efficiency to chiral metal complexes and enzymatic systems. The book begins with a summary of the first work on heterogeneous metal catalysts, which showed only the principal possibilities of enantioselective reactions. It then elaborates on metal catalysts which have enantioselectivities close to 100%. Finally, the practical utilization of chiral catalytic systems in processes of hydrogenation is described. The alpha- and beta-hydroxy carboxylic acid esters produced are precursors for manufacturing many synthones used for medicines as well as for monomers used for biodegradable polyesters, both of which have important practical applications.

The volume summarizes more than 800 scientific papers in the field of enantioselective catalytic hydrogenation reactions, mainly those using heterogeneous metal catalysts. It provides detailed explanations of special techniques for the preparation of effective dissymmetric catalysts which provide highly efficient catalytic systems. This book differs from previous publications by virtue of the recommendations for the practical utilization of recently described preparations of metal catalysts.

This book will be an invaluable resource to catalysis researchers as well as to those utilizing the technology.



Inhalt
ASYMMETRIC ADSORPTION ON MINERALS.- HETEROGENEOUS HYDROGENATION CATALYSTS BASED ON QUARTZ.- HETEROGENEOUS CATALYSTS SUPPORTED ON CHIRAL CARRIERS.- HYDROGENATION ON CATALYSTS BASED ON Ni AND BIMETALS.- ASYMMETRIC HYDROGENATION OF 2-OXOCARBOXYLIC ACID ESTERS AND UNSATURATED CARBOXYLIC ACIDS ON MODIFIED PT AND PD CATALYSTS.- ELECTROCHEMICAL ENANTIOSELECTIVE REDUCTIONS.- PRACTICAL ASYMMETRIC CATALYTIC REACTIONS.

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Produktinformationen

Titel
Heterogeneous Enantioselective Hydrogenation
Untertitel
Theory and Practice
Autor
EAN
9781402042942
ISBN
978-1-4020-4294-2
Format
Fester Einband
Herausgeber
Springer Netherlands
Genre
Chemie
Anzahl Seiten
305
Gewicht
648g
Größe
H243mm x B243mm x T157mm
Jahr
2006
Untertitel
Englisch
Auflage
2006
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